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The Zodiac Master's real name is Woo Yin. His main goal is clear: Get four Powerbands and revive the Emperor Of The Darkest Yin. He mainly goes after the Snake Powerband since he feels it should be his. He has a pet snake called King Cobra and uses it as a spy or to help him in fights.
When empowering a stolen Powerband he would normally say “Empower the Darkest Yin” followed by the band he stole, like if he stole the Snake Power band he would say "Empower the Darkest Yin, Snake". He is always a great threat to every Guardian, but Ang, the Golden Dragon, often saves the day. Despite supposedly being very powerful, he is often easily defeated even in situations in which he has the clear advantage (such as having three Powerbands to Ang only using his Dragon Powerband).
He was born in the year of the Snake and thought he was going to be the Snake Guardian. Ultimately, the Snake Powerband selected someone different (Cobra), and he chose evil as a result, much like Ang and Ling. His dream is to get all the Power bands of the Chinese Zodiac, making him invincible.